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Mid-Infrared Spectroscopy of Carbon Stars in the Small Magellanic Cloud
We have observed a sample of 36 objects in the Small Magellanic Cloud(SMC) with the Infrared Spectrometer on the Spitzer Space Telescope.Nineteen of these sources are carbon stars. An examination of the near-and mid-infrared photometry shows that the carbon-rich and oxygen-richdust sources follow two easily separated sequences. A comparison of thespectra of the 19 carbon stars in the SMC to spectra from the InfraredSpace Observatory (ISO) of carbon stars in the Galaxy revealssignificant differences. The absorption bands at 7.5 and 13.7 μm dueto C2H2 are stronger in the SMC sample, and theSiC dust emission feature at 11.3 μm is weaker. Our measurements ofthe MgS dust emission feature at 26-30 μm are less conclusive, butthis feature appears to be weaker in the SMC sample as well. All ofthese results are consistent with the lower metallicity in the SMC. Thelower abundance of SiC grains in the SMC may result in less efficientcarbon-rich dust production, which could explain the excessC2H2 gas seen in the spectra. The sources in theSMC with the strongest SiC dust emission tend to have redder infraredcolors than the other sources in the sample, which implies moreamorphous carbon, and they also tend to show stronger MgS dust emission.The weakest SiC emission features tend to be shifted to the blue; thesespectra may arise from low-density shells with large SiC grains.

Infrared photometry and evolution of mass-losing AGB stars. I. Carbon stars revisited
As part of a reanalysis of galactic Asymptotic Giant Branch (AGB) starsat infrared (IR) wavelengths, we discuss a sample (357) of carbon starsfor which mass loss rates, near-IR photometry and distance estimatesexist. For 252 sources we collected mid-IR fluxes from the MSX (6C) andthe ISO-SWS catalogues. Most stars have spectral energy distributions upto 21 μm, and some (1/3) up to 45 μm. This wide wavelengthcoverage allows us to obtain reliable bolometric magnitudes. Theproperties of our sample are discussed with emphasis on ~70 stars withastrometric distances. We show that mid-IR fluxes are crucial toestimate the magnitude of stars with dusty envelopes. We construct HRdiagrams and show that the luminosities agree fairly well with modelpredictions based on the Schwarzschild's criterion, contrary to what iswidely argued in the literature. A problem with the brightness of Cstars does not appear to exist. From the relative number of Mira andSemiregular C-variables, we argue that the switch between these classesis unlikely to be connected to thermal pulses. The relevance of the twopopulations varies with the evolution, with Miras dominating the finalstages. We also analyze mass loss rates, which increase for increasingluminosity, but with a spread that probably results from a dependence ona number of parameters (like e.g. different stellar masses and differentmechanisms powering stellar winds). Instead, mass loss rates are wellmonitored by IR colours, especially if extended to 20 μm and beyond,where AGB envelopes behave like black bodies. From these colours theevolutionary status of various classes of C stars is discussed.

CH stars at high Galactic latitudes
Carbon-rich stars of Population II, such as CH stars, can provide directinformation on the role of low- to intermediate-mass stars of the haloin early Galactic evolution. Thus accurate knowledge of the CH stellarpopulation is a critical requirement for building up scenarios for earlyGalactic chemical evolution. In the present work, we report on severalCH stars identified in a sample of faint high-latitude carbon stars fromthe Hamburg survey and discuss their medium-resolution spectra coveringthe wavelength range 4000-6800 Å. Estimation of the depths of the(1,0)12C12C λ4737 and(1,0)12C13C λ4744 bands in these starsindicates an isotopic ratio 12C/13C ~ 3, apartfrom a few exceptions; these ratios are consistent with existingtheories of CH stellar evolution. The stars of the Hamburg survey, atotal of 403 objects, were reported to be carbon star candidates withstrong C2 and CN molecular bands. In the first phase ofobservation, we acquired spectra of 91 objects. Inspection of thespectra of those objects shows 51 objects with C2 molecularbands in their spectra, of which 13 stars have low flux below about 4300Å. There are 25 objects that show weak or moderate CH and CNbands, 12 objects that show weak but detectable CH bands, and threeobjects that do not show any molecular bands due to C2, CN orCH in their spectra. Objects with C2 molecular bands and withgood signals bluewards of 4300 Åthat show prominent CH bands intheir spectra are potential candidate CH stars. There were 35 suchcandidates found in the present sample of 91 objects observed so far.The set of CH stars identified could be the targets of subsequentobservation at high resolution for a detailed and comprehensive analysisto understand their role in early Galactic chemical evolution.

Three-micron spectra of AGB stars and supergiants in nearby galaxies
The dependence of stellar molecular bands on the metallicity is studiedusing infrared L-band spectra of AGB stars (both carbon-rich andoxygen-rich) and M-type supergiants in the Large and Small MagellanicClouds (LMC and SMC) and in the Sagittarius Dwarf Spheroidal Galaxy. Thespectra cover SiO bands for oxygen-rich stars, and acetylene (C2H2), CHand HCN bands for carbon-rich AGB stars. The equivalent width ofacetylene is found to be high even at low metallicity. The high C2H2abundance can be explained with a high carbon-to-oxygen (C/O) ratio forlower metallicity carbon stars. In contrast, the HCN equivalent width islow: fewer than half of the extra-galactic carbon stars show the 3.5μm HCN band, and only a few LMC stars show high HCN equivalent width.HCN abundances are limited by both nitrogen and carbon elementalabundances. The amount of synthesized nitrogen depends on the initialmass, and stars with high luminosity (i.e. high initial mass) could havea high HCN abundance. CH bands are found in both the extra-galactic andGalactic carbon stars. One SMC post-AGB star, SMC-S2, shows the 3.3μm PAH band. This first detection of a PAH band from an SMC post-AGBstar confirms PAHs can form in these low-metallicity stars. None of theoxygen-rich LMC stars show SiO bands, except one possible detection in alow quality spectrum. The limits on the equivalent widths of the SiObands are below the expectation of up to 30 Å for LMC metallicity.Several possible explanations are discussed, mostly based on the effectof pulsation and circumstellar dust. The observations imply that LMC andSMC carbon stars could reach mass-loss rates as high as their Galacticcounterparts, because there are more carbon atoms available and morecarbonaceous dust can be formed. On the other hand, the lack of SiOsuggests less dust and lower mass-loss rates in low-metallicityoxygen-rich stars. The effect on the ISM dust enrichment is discussed.

CHARM2: An updated Catalog of High Angular Resolution Measurements
We present an update of the Catalog of High Angular ResolutionMeasurements (CHARM, Richichi & Percheron \cite{CHARM}, A&A,386, 492), which includes results available until July 2004. CHARM2 is acompilation of direct measurements by high angular resolution methods,as well as indirect estimates of stellar diameters. Its main goal is toprovide a reference list of sources which can be used for calibrationand verification observations with long-baseline optical and near-IRinterferometers. Single and binary stars are included, as are complexobjects from circumstellar shells to extragalactic sources. The presentupdate provides an increase of almost a factor of two over the previousedition. Additionally, it includes several corrections and improvements,as well as a cross-check with the valuable public release observationsof the ESO Very Large Telescope Interferometer (VLTI). A total of 8231entries for 3238 unique sources are now present in CHARM2. Thisrepresents an increase of a factor of 3.4 and 2.0, respectively, overthe contents of the previous version of CHARM.The catalog is only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/431/773

The mass loss of C-rich giants
The mass loss rates, expansion velocities and dust-to-gas density ratiosfrom millimetric observations of 119 carbon-rich giants are compared, asfunctions of stellar parameters, to the predictions of recenthydrodynamical models. Distances and luminosities previously estimatedfrom HIPPARCOS data, masses from pulsations and C/O abundance ratiosfrom spectroscopy, and effective temperatures from a new homogeneousscale, are used. Predicted and observed mass loss rates agree fairlywell, as functions of effective temperature. The signature of the massrange M≤4 Mȯ of most carbon-rich AGB stars is seenas a flat portion in the diagram of mass loss rate vs. effectivetemperature. It is flanked by two regions of mass loss rates increasingwith decreasing effective temperature at nearly constant stellar mass.Four stars with detached shells, i.e. episodic strong mass loss, andfive cool infrared carbon-rich stars with optically-thick dust shells,have mass loss rates much larger than predicted values. The latter(including CW Leo) could be stars of smaller masses (M≃ 1.5-2.5Mȯ) while M≃ 4 Mȯ is indicated formost of the coolest objects. Among the carbon stars with detachedshells, R Scl returned to a predicted level (16 times lower) accordingto recent measurements of the central source. The observed expansionvelocities are in agreement with the predicted velocities at infinity ina diagram of velocities vs. effective temperature, provided the carbonto oxygen abundance ratio is 1≤ɛ C/ɛO≤2, i.e. the range deduced from spectra and modelatmospheres of those cool variables. Five stars with detached shellsdisplay expansion velocities about twice that predicted at theireffective temperature. Miras and non-Miras do populate the same locus inboth diagrams at the present accuracy. The predicted dust-to-gas densityratios are however about 2.2 times smaller than the values estimatedfrom observations. Recent drift models can contribute to minimize thediscrepancy since they include more dust. Simple approximate formulaeare proposed.This research has made use of the Simbad database operated at CDS.Partially based on data from the ESA HIPPARCOS astrometry satellite.Table 3 is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/429/235

Dynamic model atmospheres of AGB stars. IV. A comparison of synthetic carbon star spectra with observations
We have calculated synthetic opacity sampling spectra for carbon-richAsymptotic Giant Branch (AGB) stars based on dynamic model atmosphereswhich couple time-dependent dynamics and frequency-dependent radiativetransfer, as presented in the third paper of this series. We include themolecules CO, CH, CN, C2, CS, HCN, C2H2and C3 in our calculations, both when computing theatmospheric structures, and the synthetic spectra. A comparison of thesynthetic spectra with various observed colours and spectra in thewavelength range between 0.5 and 25 μm,of TX Psc, WZ Cas, V460 Cyg, TLyr and S Cep is presented. We obtain good agreement betweenobservations gathered at different phases and synthetic spectra of onesingle hydrodynamical model for each star in the wavelength regionbetween 0.5 and 5 μm. At longer wavelengths our models showing massloss offer a first self-consistent qualitative explanation of why astrong feature around 14 μm, which is predicted by all hydrostaticmodels as well as dynamical models showing no mass loss, is missing inobserved AGB carbon star spectra.

Molecular and dust features of 29 SiC carbon AGB stars
We have reduced and analyzed the Infrared Space Observatory (ISO)Short-Wavelength Spectrometer (SWS) spectra of 29 infrared carbon starswith a silicon carbide feature at 11.30 μm, 17 of which have not beenpreviously published. Absorption or emission features of C2,HCN, C2H2, C3 and silicon carbide (SiC)have been identified in all 17 unpublished carbon stars. In addition,two unidentified absorption features at 3.50 and 3.65 μm are listedfor the first time in this paper. We classify these 29 carbon stars intogroups A, B, C and D according to the shapes of their spectral energydistribution, and this classification seems to show an evolutionarysequence of carbon stars with an SiC feature. Moreover we have found thefollowing results for the different groups: on average, the relativeintegrated flux of the 3.05 μm C2H2+HCNabsorption feature increases gradually from group A to B and C; that ofthe 5.20 μm C3 absorption feature becomes gradually weakerfrom group A to B and C; that of the 11.30 μm SiC emission featureincreases gradually from group A to B and C but weakens in group D; andin contrast, that of the 13.70 μm C2H2absorption feature weakens gradually from group A to B and C but becomesstronger in group D. We suggest that the evolution of the IR spectra ofcarbon stars along the sequence A to D is a result of the followingphenomena: as the near-IR black-body temperature (Tnir)decreases, the circumstellar envelope becomes thicker; also theeffective temperature (Teff) of the photosphere of thecentral star decreases gradually and the C/O ratio increases from A toB.Based on observations with ISO, an ESA project with instruments fundedby ESA Member States (especially the PI countries: France, Germany, TheNetherlands and the UK) with the participation of ISAS and NASA.

Spectral Classification of Faint Carbon Stars
R--N classification of 187 faint carbon stars is based on the classicalcriteria adjusted to the yellow-red spectral region, with two newcriteria added -- the ratios of the red CN bands 6206/6332 (Å) and6478/6631 (Å).

New Laboratory Spectra of Isolated β-SiC Nanoparticles: Comparison with Spectra Taken by the Infrared Space Observatory
We present new laboratory infrared spectra of matrix-isolated β-SiCnanoparticles, which perfectly match the band profile of the 11+ μmfeature observed in carbon stars. The new laboratory spectra differ inthe shape of the band profile from former measurements of SiCnanoparticles thanks to the matrix-isolation technique which allows toobtain spectra of nonagglomerated particles. The final spectra arecorrected for the influence of the surrounding medium (argon-matrix) bya computational technique proposed by Papoular et al. (1998).Furthermore, we study the influence of nitrogen incorporation into theSiC lattice, which introduces a strong near-infrared absorption owing tosurface-plasmon excitation (Mutschke et al. 1999). Our laboratoryspectra are compared with Infrared Space Observatory observations ofseveral carbon stars showing an 11 μm feature either in emission orin absorption. We discuss the implications of the new laboratory resultsfor the interpretation of the spectra of carbon stars.Based on observations with ISO, an ESA project with instruments fundedby ESA Member States (especially the PI countries: France, Germany, theNetherlands, and the UK) and with the participation of ISAS and NASA.The SWS is a joint project of SRON and MPE.

Reprocessing the Hipparcos data of evolved stars. III. Revised Hipparcos period-luminosity relationship for galactic long-period variable stars
We analyze the K band luminosities of a sample of galactic long-periodvariables using parallaxes measured by the Hipparcos mission. Theparallaxes are in most cases re-computed from the Hipparcos IntermediateAstrometric Data using improved astrometric fits and chromaticitycorrections. The K band magnitudes are taken from the literature andfrom measurements by COBE, and are corrected for interstellar andcircumstellar extinction. The sample contains stars of several spectraltypes: M, S and C, and of several variability classes: Mira, semiregularSRa, and SRb. We find that the distribution of stars in theperiod-luminosity plane is independent of circumstellar chemistry, butthat the different variability types have different P-L distributions.Both the Mira variables and the SRb variables have reasonablywell-defined period-luminosity relationships, but with very differentslopes. The SRa variables are distributed between the two classes,suggesting that they are a mixture of Miras and SRb, rather than aseparate class of stars. New period-luminosity relationships are derivedbased on our revised Hipparcos parallaxes. The Miras show a similarperiod-luminosity relationship to that found for Large Magellanic CloudMiras by Feast et al. (\cite{Feast-1989:a}). The maximum absolute Kmagnitude of the sample is about -8.2 for both Miras and semi-regularstars, only slightly fainter than the expected AGB limit. We show thatthe stars with the longest periods (P>400 d) have high mass lossrates and are almost all Mira variables.Based on observations from the Hipparcos astrometric satellite operatedby the European Space Agency (ESA \cite{Hipparcos}).Table \ref{Tab:data1} is only available in electronic form at the CDSvia anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/403/993

Hipparcos red stars in the HpV_T2 and V I_C systems
For Hipparcos M, S, and C spectral type stars, we provide calibratedinstantaneous (epoch) Cousins V - I color indices using newly derivedHpV_T2 photometry. Three new sets of ground-based Cousins V I data havebeen obtained for more than 170 carbon and red M giants. These datasetsin combination with the published sources of V I photometry served toobtain the calibration curves linking Hipparcos/Tycho Hp-V_T2 with theCousins V - I index. In total, 321 carbon stars and 4464 M- and S-typestars have new V - I indices. The standard error of the mean V - I isabout 0.1 mag or better down to Hp~9 although it deteriorates rapidly atfainter magnitudes. These V - I indices can be used to verify thepublished Hipparcos V - I color indices. Thus, we have identified ahandful of new cases where, instead of the real target, a random fieldstar has been observed. A considerable fraction of the DMSA/C and DMSA/Vsolutions for red stars appear not to be warranted. Most likely suchspurious solutions may originate from usage of a heavily biased color inthe astrometric processing.Based on observations from the Hipparcos astrometric satellite operatedby the European Space Agency (ESA 1997).}\fnmsep\thanks{Table 7 is onlyavailable in electronic form at the CDS via anonymous ftp tocdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/397/997

s-Process Nucleosynthesis in Carbon Stars
We present the first detailed and homogeneous analysis of the s-elementcontent in Galactic carbon stars of N type. Abundances of Sr, Y, Zr(low-mass s-elements, or ls), Ba, La, Nd, Sm, and Ce (high-masss-elements, or hs) are derived using the spectral synthesis techniquefrom high-resolution spectra. The N stars analyzed are of nearly solarmetallicity and show moderate s-element enhancements, similar to thosefound in S stars, but smaller than those found in the only previoussimilar study (Utsumi 1985), and also smaller than those found insupergiant post-asymptotic giant branch (post-AGB) stars. This is inagreement with the present understanding of the envelope s-elementenrichment in giant stars, which is increasing along the spectralsequence M-->MS-->S-->SC-->C during the AGB phase. Wecompare the observational data with recent s-process nucleosynthesismodels for different metallicities and stellar masses. Good agreement isobtained between low-mass AGB star models (M<~3 Msolar)and s-element observations. In low-mass AGB stars, the13C(α, n)16O reaction is the main source ofneutrons for the s-process a moderate spread, however, must exist in theabundance of 13C that is burnt in different stars. Bycombining information deriving from the detection of Tc, the infraredcolors, and the theoretical relations between stellar mass, metallicity,and the final C/O ratio, we conclude that most (or maybe all) of the Nstars studied in this work are intrinsic, thermally pulsing AGB stars;their abundances are the consequence of the operation of third dredge-upand are not to be ascribed to mass transfer in binary systems.

The ISO-SWS post-helium atlas of near-infrared stellar spectra
We present an atlas of near-infrared spectra (2.36 mu m-4.1 mu m) of ~300 stars at moderate resolution (lambda /delta lambda ~ 1500-2000). Thespectra were recorded using the Short-Wavelength Spectrometer aboard theInfrared Space Observatory (ISO-SWS). The bulk of the observations wereperformed during a dedicated observation campaign after the liquidhelium depletion of the ISO satellite, the so-called post-heliumprogramme. This programme was aimed at extending the MK-classificationto the near-infrared. Therefore the programme covers a large range ofspectral types and luminosity classes. The 2.36 mu m-4.05 mu m region isa valuable spectral probe for both hot and cool stars. H I lines(Bracket, Pfund and Humphreys series), He I and He II lines, atomiclines and molecular lines (CO, H2O, NH, OH, SiO, HCN,C2H2, ...) are sensitive to temperature, gravityand/or the nature of the outer layers of the stellar atmosphere(outflows, hot circumstellar discs, etc.). Another objective of theprogramme was to construct a homogeneous dataset of near-infraredstellar spectra that can be used for population synthesis studies ofgalaxies. At near-infrared wavelengths these objects emit the integratedlight of all stars in the system. In this paper we present the datasetof post-helium spectra completed with observations obtained during thenominal operations of the ISO-SWS. We discuss the calibration of the SWSdata obtained after the liquid helium boil-off and the data reduction.We also give a first qualitative overview of how the spectral featuresin this wavelength range change with spectral type. The dataset isscrutinised in two papers on the quantitative classification ofnear-infrared spectra of early-type stars ({Lenorzer} et al.\cite{lenorzer:2002a}) and late-type stars (Vandenbussche et al., inprep). Based on observations with ISO, an ESA project with instrumentsfunded by ESA Members States (especially the PI countries France,Germany, the Netherlands and the United Kingdom) and with theparticipation of ISAS and NASA. The full atlas is available inelectronic form at www.edpsciences.org Table 1 is only available inelectronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr(130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?/A+A/390/1033

Carbon-rich giants in the HR diagram and their luminosity function
The luminosity function (LF) of nearly 300 Galactic carbon giants isderived. Adding BaII giants and various related objects, about 370objects are located in the RGB and AGB portions of the theoretical HRdiagram. As intermediate steps, (1) bolometric corrections arecalibrated against selected intrinsic color indices; (2) the diagram ofphotometric coefficients 1/2 vs. astrometric trueparallaxes varpi are interpreted in terms of ranges of photosphericradii for every photometric group; (3) coefficients CR andCL for bias-free evaluation of mean photospheric radii andmean luminosities are computed. The LF of Galactic carbon giantsexhibits two maxima corresponding to the HC-stars of the thick disk andto the CV-stars of the old thin disk respectively. It is discussed andcompared to those of carbon stars in the Magellanic Clouds and Galacticbulge. The HC-part is similar to the LF of the Galactic bulge,reinforcing the idea that the Bulge and the thick disk are part of thesame dynamical component. The CV-part looks similar to the LF of theLarge Magellanic Cloud (LMC), but the former is wider due to thesubstantial errors on HIPPARCOS parallaxes. The obtained meanluminosities increase with increasing radii and decreasing effectivetemperatures, along the HC-CV sequence of photometric groups, except forHC0, the earliest one. This trend illustrates the RGB- and AGB-tracks oflow- and intermediate-mass stars for a range in metallicities. From acomparison with theoretical tracks in the HR diagram, the initial massesMi range from about 0.8 to 4.0 Msun for carbongiants, with possibly larger masses for a few extreme objects. A largerange of metallicities is likely, from metal-poor HC-stars classified asCH stars on the grounds of their spectra (a spheroidal component), tonear-solar compositions of many CV-stars. Technetium-rich carbon giantsare brighter than the lower limit Mbol =~ -3.6+/- 0.4 andcentered at =~-4.7+0.6-0.9 at about =~(2935+/-200) K or CV3-CV4 in our classification. Much like the resultsof Van Eck et al. (\cite{vaneck98}) for S stars, this confirms theTDU-model of those TP-AGB stars. This is not the case of the HC-stars inthe thick disk, with >~ 3400 K and>~ -3.4. The faint HC1 and HC2-stars( =~ -1.1+0.7-1.0) arefound slightly brighter than the BaII giants ( =~-0.3+/-1.3) on average. Most RCB variables and HdC stars range fromMbol =~ -1 to -4 against -0.2 to -2.4 for those of the threepopulation II Cepheids in the sample. The former stars show the largestluminosities ( <~ -4 at the highest effectivetemperatures (6500-7500 K), close to the Mbol =~ -5 value forthe hot LMC RCB-stars (W Men and HV 5637). A full discussion of theresults is postponed to a companion paper on pulsation modes andpulsation masses of carbon-rich long period variables (LPVs; Paper IV,present issue). This research has made use of the Simbad databaseoperated at CDS, Strasbourg, France. Partially based on data from theESA HIPPARCOS astrometry satellite. Table 2 is only available inelectronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr(130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/390/967

The carrier of the ``30'' mu m emission feature in evolved stars. A simple model using magnesium sulfide
We present 2-45 mu m spectra of a large sample of carbon-rich evolvedstars in order to study the ``30'' mu m feature. We find the ``30'' mu mfeature in a wide range of sources: low mass loss carbon stars, extremecarbon-stars, post-AGB objects and planetary nebulae. We extract theprofiles from the sources by using a simple systematic approach to modelthe continuum. We find large variations in the wavelength and width ofthe extracted profiles of the ``30'' mu m feature. We modelled the wholerange of profiles in a simple way by using magnesium sulfide (MgS) dustgrains with a MgS grain temperature different from the continuumtemperature. The systematic change in peak positions can be explained bycooling of MgS grains as the star evolves off the AGB. In severalsources we find that a residual emission excess at ~ 26 mu m can also befitted using MgS grains but with a different grains shape distribution.The profiles of the ``30'' mu m feature in planetary nebulae arenarrower than our simple MgS model predicts. We discuss the possiblereasons for this difference. We find a sample of warm carbon-stars withvery cold MgS grains. We discuss possible causes for this phenomenon. Wefind no evidence for rapid destruction of MgS during the planetarynebula phase and conclude that the MgS may survive to be incorporated inthe ISM. Based on observations obtained with ISO, an ESA project withinstruments funded by ESA Member states (especially the PI countries:France, Germany, The Netherlands and the United Kingdom) with theparticipation of ISAS and NASA. Appendix A (Figs. A.1 and A.2) is onlyavailable in electronic form at http://www.edpsciences.org

CHARM: A Catalog of High Angular Resolution Measurements
The Catalog of High Angular Resolution Measurements (CHARM) includesmost of the measurements obtained by the techniques of lunaroccultations and long-baseline interferometry at visual and infraredwavelengths, which have appeared in the literature or have otherwisebeen made public until mid-2001. A total of 2432 measurements of 1625sources are included, along with extensive auxiliary information. Inparticular, visual and infrared photometry is included for almost allthe sources. This has been partly extracted from currently availablecatalogs, and partly obtained specifically for CHARM. The main aim is toprovide a compilation of sources which could be used as calibrators orfor science verification purposes by the new generation of largeground-based facilities such as the ESO Very Large Interferometer andthe Keck Interferometer. The Catalog is available in electronic form atthe CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/386/492, and from theauthors on CD-Rom.

CO 1st overtone spectra of cool evolved stars: Diagnostics for hydrodynamic atmosphere models
We present spectra covering the wavelength range 2.28 to 2.36 mu m at aresolution of Delta lambda = 0.0007 mu m (or R = 3500) for a sample of24 cool evolved stars. The sample comprises 8 M supergiants, 5 M giants,3 S stars, 6 carbon stars, and 2 RV Tauri variables. The wavelengthscovered include the main parts of the 12C16O v =2-0 and 3-1 overtone bands, as well as the v = 4-2 and 13CO v= 2-0 bandhead regions. CO lines dominate the spectrum for all the starsobserved, and at this resolution most of the observed features can beidentified with individual CO R- or P-branch lines or blends. Theobserved transitions arise from a wide range of energy levels extendingfrom the ground state to E/k > 20 000 K. We looked for correlationsbetween the intensities of various CO absorption line features and otherstellar properties, including IR colors and mass loss rates. Two usefulCO line features are the v = 2-0 R14 line, and the CO v = 2-0 bandhead.The intensity of the 2-0 bandhead shows a trend with K-[12] color suchthat the reddest stars (K-[12] > 3 mag) exhibit a wide range in 2-0bandhead depth, while the least reddened have the deepest 2-0 bandheads,with a small range of variation from star to star. Gas mass loss ratesfor both the AGB stars and the red supergiants in our sample correlatewith the K-[12] color, consistent with other studies. The data implythat stars with dot M_gas < 5x 10-7 Msuny-1 exhibit a much narrower range in the relative strengthsof CO 2-0 band features than stars with higher mass loss rates. Therange in observed spectral properties implies that there are significantdifferences in atmospheric structure among the stars in this sample.Figures 4-9, 11-14, 16, 17, 19-21, 23, 24 are only avalaible inelectronic form at http://www.edpsciences.org

Stars with the Largest Hipparcos Photometric Amplitudes
A list of the 2027 stars that have the largest photometric amplitudes inHipparcos Photometry shows that most variable stars are all Miras. Thepercentage of variable types change as a function of amplitude. Thiscompilation should also be of value to photometrists looking forrelatively unstudied, but large amplitude stars.

General Catalog of Galactic Carbon Stars by C. B. Stephenson. Third Edition
The catalog is an updated and revised version of Stephenson's Catalogueof Galactic Cool Carbon Stars (2nd edition). It includes 6891 entries.For each star the following information is given: equatorial (2000.0)and galactic coordinates, blue, visual and infrared magnitudes, spectralclassification, references, designations in the most significantcatalogs and coordinate precision classes. The main catalog issupplemented by remarks containing information for which there was noplace in entries of the main part, as well as some occasional notesabout the peculiarities of specific stars.

The 85Kr s-Process Branching and the Mass of Carbon Stars
We present new spectroscopic observations for a sample of C(N)-type redgiants. These objects belong to the class of asymptotic giant branchstars, experiencing thermal instabilities in the He-burning shell(thermal pulses). Mixing episodes called third dredge-up enrich thephotosphere with newly synthesized 12C in the He-rich zone,and this is the source of the high observed ratio between carbon andoxygen (C/O>=1 by number). Our spectroscopic abundance estimatesconfirm that, in agreement with the general understanding of the lateevolutionary stages of low- and intermediate-mass stars, carbonenrichment is accompanied by the appearance of s-process elements in thephotosphere. We discuss the details of the observations and of thederived abundances, focusing in particular on rubidium, a neutrondensity sensitive element, and on the s-elements Sr, Y, and Zr belongingto the first s-peak. The critical reaction branching at 85Kr,which determines the relative enrichment of the studied species, isdiscussed. Subsequently, we compare our data with recent models fors-processing in thermally pulsing asymptotic giant branch stars, atmetallicities relevant for our sample. A remarkable agreement betweenmodel predictions and observations is found. Thanks to the differentneutron density prevailing in low- and intermediate-mass stars,comparison with the models allows us to conclude that most C(N) starsare of low mass (M<~3 Msolar). We also analyze the12C/13C ratios measured, showing that most of themcannot be explained by canonical stellar models. We discuss how thisfact would require the operation of an ad hoc additional mixing,currently called cool bottom process, operating only in low-mass starsduring the first ascent of the red giant branch and, perhaps, alsoduring the asymptotic giant branch.

Long period variable stars: galactic populations and infrared luminosity calibrations
In this paper HIPPARCOS astrometric and kinematic data are used tocalibrate both infrared luminosities and kinematical parameters of LongPeriod Variable stars (LPVs). Individual absolute K and IRAS 12 and 25luminosities of 800 LPVs are determined and made available in electronicform. The estimated mean kinematics is analyzed in terms of galacticpopulations. LPVs are found to belong to galactic populations rangingfrom the thin disk to the extended disk. An age range and a lower limitof the initial mass is given for stars of each population. A differenceof 1.3 mag in K for the upper limit of the Asymptotic Giant Branch isfound between the disk and old disk galactic populations, confirming itsdependence on the mass in the main sequence. LPVs with a thin envelopeare distinguished using the estimated mean IRAS luminosities. The levelof attraction (in the classification sense) of each group for the usualclassifying parameters of LPVs (variability and spectral types) isexamined. Table only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/374/968 or via ASTRIDdatabase (http://astrid.graal.univ-montp2.fr).

The effective temperatures of carbon-rich stars
We evaluate effective temperatures of 390 carbon-rich stars. Theinterstellar extinction on their lines of sights was determined andcircumstellar contributions derived. The intrinsic (dereddened) spectralenergy distributions (SEDs) are classified into 14 photometric groups(HCi, CVj and SCV with i=0,5 and j=1,7). The newscale of effective temperatures proposed here is calibrated on the 54angular diameters (measured on 52 stars) available at present from lunaroccultations and interferometry. The brightness distribution on stellardiscs and its influence on diameter evaluations are discussed. Theeffective temperatures directly deduced from those diameters correlatewith the classification into photometric groups, despite the large errorbars on diameters. The main parameter of our photometric classificationis thus effective temperature. Our photometric < k right >1/2 coefficients are shown to be angular diameters on arelative scale for a given photometric group, (more precisely for agiven effective temperature). The angular diameters are consistent withthe photometric data previously shown to be consistent with the trueparallaxes from HIPPARCOS observations (Knapik, et al. \cite{knapik98},Sect. 6). Provisional effective temperatures, as constrained by asuccessful comparison of dereddened SEDs from observations to modelatmosphere predictions, are in good agreement with the values directlycalculated from the observed angular diameters and with those deducedfrom five selected intrinsic color indices. These three approaches wereused to calibrate a reference angular diameter Phi 0 and theassociated coefficient CT_eff. The effective temperatureproposed for each star is the arithmetic mean of two estimates, one(``bolometric'') from a reference integrated flux F0, theother (``spectral'') from calibrated color indices which arerepresentative of SED shapes. Effective temperatures for about 390carbon stars are provided on this new homogeneous scale, together withvalues for some stars classified with oxygen-type SEDs with a total of438 SEDs (410 stars) studied. Apparent bolometric magnitudes are given.Objects with strong infrared excesses and optically thick circumstellardust shells are discussed separately. The new effective temperaturescale is shown to be compatible and (statistically) consistent with thesample of direct values from the observed angular diameters. Theeffective temperatures are confirmed to be higher than the mean colortemperatures (from 140 to 440 K). They are in good agreement with thepublished estimates from the infrared flux method forTeff>= 3170 K, while an increasing discrepancy is observedtoward lower temperatures. As an illustration of the efficiency of thephotometric classification and effective temperature scale, the C/Oratios and the Merrill-Sanford (M-S) band intensities are investigated.It is shown that the maximum value, mean value and dispersion of C/Oincrease along the photometric CV-sequence, i.e. with decreasingeffective temperature. The M-S bands of SiC2 are shown tohave a transition from ``none'' to ``strong'' at Teff =~(2800+/- 150right ) K. Simultaneously, with decreasing effectivetemperature, the mean C/O ratio increases from 1.04 to 1.36, thetransition in SiC2 strength occurring while 1.07<= C/O<= 1.18. This research has made use of the Simbad database operatedat CDS, Strasbourg, France. Table 10 is only available in electronicform at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5)}or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/369/178

Models of circumstellar molecular radio line emission. Mass loss rates for a sample of bright carbon stars
Using a detailed radiative transfer analysis, combined with an energybalance equation for the gas, we have performed extensive modelling ofcircumstellar CO radio line emission from a large sample of opticallybright carbon stars, originally observed by Olofsson et al. (ApJS, 87,267). Some new observational results are presented here. We determinesome of the basic parameters that characterize circumstellar envelopes(CSEs), e.g., the stellar mass loss rate, the gas expansion velocity,and the kinetic temperature structure of the gas. Assuming a sphericallysymmetric CSE with a smooth gas density distribution, created by acontinuous mass loss, which expands with a constant velocity we are ableto model reasonably well 61 of our 69 sample stars. The derived massloss rates depend crucially on the assumptions in the circumstellarmodel, of which some can be constrained if enough observational dataexist. Therefore, a reliable mass loss rate determination for anindividual star requires, in addition to a detailed radiative transferanalysis, good observational constraints in the form of multi-lineobservations and radial brightness distributions. In our analysis we usethe results of a model for the photodissociation of circumstellar CO byMamon et al. (1988). This leads to model fits to observed radialbrightness profiles that are, in general, very good, but there are alsoa few cases with clear deviations, which suggest departures from asimple r-2 density law. The derived mass loss rates spanalmost four orders of magnitude, from ~ 5 10-9Msun yr-1 up to ~ 2 10-5Msun yr-1, with the median mass loss rate being ~3 10-7 Msun yr-1. We estimate that themass loss rates are typically accurate to ~ 50% within the adoptedcircumstellar model. The physical conditions prevailing in the CSEs varyconsiderably over such a large range of mass loss rates. Among otherthings, it appears that the dust-to-gas mass ratio and/or the dustproperties change with the mass loss rate. We find that the mass lossrate and the gas expansion velocity are well correlated, and that bothof them clearly depend on the pulsational period and (with largerscatter) the stellar luminosity. Moreover, the mass loss rate correlatesweakly with the stellar effective temperature, in the sense that thecooler stars tend to have higher mass loss rates, but there seems to beno correlation with the stellar C/O-ratio. We conclude that the massloss rate increases with increased regular pulsation and/or luminosity,and that the expansion velocity increases as an effect of increasingmass loss rate (for low mass loss rates) and luminosity. Five, of theremaining eight, sample stars have detached CSEs in the form ofgeometrically thin CO shells. The present mass loss rates and shellmasses of these sources are estimated. Finally, in three cases weencounter problems using our model. For two of these sources there areindications of significant departures from overall spherical symmetry ofthe CSEs. Carbon stars on the AGB are probably important in returningprocessed gas to the ISM. We estimate that carbon stars of the typeconsidered here annually return ~ 0.05 Msun of gas to theGalaxy, but more extreme carbon stars may contribute an order ofmagnitude more. However, as for the total carbon budget of the Galaxy,carbon stars appear to be of only minor importance. Presented in thispaper is observational data collected using the Swedish-ESOsubmillimetre telescope, La Silla, Chile, the 20\,m telescope at OnsalaSpace Observatory, Chalmers Tekniska Högskola, Sweden, and the NRAO12\,m telescope located at Kitt Peak, USA.}

Catalogue of Apparent Diameters and Absolute Radii of Stars (CADARS) - Third edition - Comments and statistics
The Catalogue, available at the Centre de Données Stellaires deStrasbourg, consists of 13 573 records concerning the results obtainedfrom different methods for 7778 stars, reported in the literature. Thefollowing data are listed for each star: identifications, apparentmagnitude, spectral type, apparent diameter in arcsec, absolute radiusin solar units, method of determination, reference, remarks. Commentsand statistics obtained from CADARS are given. The Catalogue isavailable in electronic form at the CDS via anonymous ftp tocdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcar?J/A+A/367/521

Modeling of C stars with core/mantle grains: Amorphous carbon + SiC
A set of 45 dust envelopes of carbon stars has been modeled. Among them,34 were selected according to their dust envelope class (as suggested bySloan et al. \cite{Sloan98}) and 11 are extreme carbon stars. The modelswere performed using a code that describes the radiative transfer indust envelopes considering core/mantle grains composed by an alpha -SiCcore and an amorphous carbon (A.C.) mantle. In addition, we have alsocomputed models with a code that considers two kinds of grains - alpha-SiC and A.C. - simultaneously. Core-mantle grains seem to fit dustenvelopes of evolved carbon stars, while two homogeneous grains are moreable to reproduce thinner dust envelopes. Our results suggest that thereexists an evolution of dust grains in the carbon star sequence. In thebeginning of the sequence, grains are mainly composed of SiC andamorphous carbon; with dust envelope evolution, carbon grains are coatedin SiC. This phenomena could perhaps explain the small quantity of SiCgrains observed in the interstellar medium. However, in this work weconsider only alpha -SiC grains, and the inclusion of beta -SiC grainscan perhaps change some of these results.

Circumstellar dust shells around long-period variables. IX. Molecular layers resulting from shocked carbon-rich atmospheres
The existence of warm zones of an enhanced molecular content surroundingthe photospheres of AGB stars has been postulated to explain observedmolecular absorption/emission components which are in excess of theresults obtained from classical hydrostatic model atmospheres. We haveanalyzed the chemical equilibrium molecular composition oftime-dependent models of carbon-rich circumstellar envelopes for variouscombinations of the stellar parameters and found that groups ofmolecules appear to be present in different zones with temporallyvarying temperature and density. The regions of enhanced molecularabundances are situated between the stellar photosphere and thecircumstellar dust shell. In the models, these zones are produced by thelevitation of the atmospheric gas due to the dissipation of shock wavesand/or due to radiation pressure on molecules and dust.

Atmospheres of carbon stars. Models and observations.
Not Available

On the distance and mass-loss rate of carbon stars showing the silicon carbide emission feature
The distances and the mass-loss rates of carbon stars are in generalvery poorly known. The various estimates of the distances, taken fromthe general literature, show considerable discrepancies, while theevaluations of the mass-loss rates can be in error by more than an orderof magnitude. In this work we have evaluated these two important stellarparameters for a previously selected sample of 55 carbon stars showingthe 11.3 mu m band, commonly attributed to silicon carbide (SiC) grains.To perform the calculation we have used the values of geometrical andphysical parameters of these sources obtained from the best fits oftheir observed spectra. Using the distance values derived in this wayand the 11.3 mu m band intensity, we have evaluated the absolute bandstrength and we have found that, in agreement with other authors, thereis a correlation between this quantity and the mass-loss rate. Thiscorrelation can be very useful to determine the mass-loss rate of othercarbon stars not included in our sample, by means of the intensity ofthe SiC band, without using the usual technique based on COobservations. The same procedure can be conveniently applied to the sameas well as to other carbon stars, whose spectra will be available to thecommunity in the next future (i.e. the infrared spectra of sourcesobserved by the Infrared Satellite Observatory, ISO).

ISO-SWS spectra of the carbon stars TX Psc, V460 Cyg, and TT Cyg
During our open and discretionary time ISO programs we have observed anumber of carbon-rich and oxygen-rich AGB stars. We present here ahydrostatic analysis of 3 carbon rich stars, TX Psc, V460 Cyg, and TTCyg, which show only modest variability. We identify absorption featuresof the molecules C_2, CN, CH, CO, CS, HCN, C_2H_2, and C_3 in the threestars. The relative intensities of the corresponding bands put strictlimits on the possible values of T_eff, log g, and C/O. In particularthe ratio of the intensity of the 3 mu m band (due to HCN and C_2H_2)and the 5 mu m band (due to CO and C_3) is a sensitive measure of theC/O ratio. We show that our model atmospheres and correspondingsynthetic spectra are able to reproduce the observed spectra quiteaccurately from the visual region through the infrared out toapproximately 10 mu m. Beyond 10 mu m the flux in the observed spectraincreases compared to the computed spectra, and the photospheric 14 mu mband dominated by C_2H_2 and HCN is almost absent in the observedspectra whereas it is very strong in the synthetic ones. Thisdiscrepancy is not an artefact in the reduction or in the SWS responsefunction, but a physical phenomenon in the stars, which does not appearin oxygen-rich giants. We exclude a so-called ``warm molecularenvelope'' as an explanation of the discrepancies, and suggest that theflux excess at long wavelengths can be interpreted as clumps of ~ 500 Kdense material which obscures about 10% of the photosphere. Weakspectral features seen around 13.7 mu m can be understood as even coolergas, rich in C_2H_2, above the clumps. Other possible models to explainthe long wavelength discrepancy between the computed and observedspectra need to be explored too. Based on observations with ISO, an ESAproject with instruments funded by ESA member states (especially the PIcountries: France, Germany, the Netherlands and the United Kingdom) andwith the participation of ISAS and NASA

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